Appendix 2
Acidifying irrigation water to prevent calcium carbonate scale formation…
When and how to do it
- If necessary, irrigation water can be acidified to neutralize excess carbonate (CO32-) and bicarbonate (HCO3-) that occurs naturally in waters originating from limestone aquifers.
- Excess carbonate is most likely to occur wherever the irrigation water source is a limestone aquifer.
- How to determining if a potential problem exists:
- The best way to determine if irrigation water contains an excessive carbonate concentration is to have the water tested for liming potential by titrating it with an acid.
- If titration is not available, the next best way is to estimate the carbonate concentration from the calcium and magnesium concentrations.
- This estimation assumes that most of the Ca and Mg in a water sample is a result of dissolved Ca and Mg carbonates.
- To estimate total carbonates (bases) from a Ca/Mg water test, use this formula:
meq/L of bases = (ppm Ca x 0.05) + (ppm Mg x 0.083).
- If a water test does not show Ca/Mg concentrations but does show hardness (as in Table 1), dividing hardness by 50 provides a good estimate of bases in meq/L.
- Determining how much acid to apply to irrigation water is a several step process. The amount depends on the bicarbonate concentration in the water and the strength of the acid used. Properties of common acids are shown in Table A-2-1.
- Use the following steps to calculate the amount of acid to apply:
- Have your irrigation water sample analyzed for total carbonates.
- From Table A-2-1, determine the appropriate rate calculation factor for the acid to be used./li>
- Multiply the factor by the milliequivalents of base per liter (meq/L) that the water contains.
- The result is the mL of acid that should be applied per 100 gallons of irrigation water. To convert from mL to fluid ounces, divide mL by 29.6.
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- This acid addition will neutralize 80% of the bases in the water. It is not necessary to neutralize 100% to make the bicarbonate problem insignificant. Not trying to neutralize all of the bicarbonates allows some room for error. The risk of over acidification is not worth it.
- Acids are highly toxic and corrosive chemicals, and should be handled with great care. Precautions when using acids include:
- Use goggles and protective clothing when handling.
- When mixing acids with water, always add the acid to the water, never vice-versa, in a well-ventilated area.
- Dilute concentrated acid with water in a non-metal mixing tank prior to injecting into the irrigation system.
- Avoid over-application, which can severely damage plants.